ChemInform Abstract: Synthesis of Silicon-Functionalized Dimethylsilyl Enol Ethers from Ketones

Autor:	M. W. Rathke, Paul D. Weipert
Rok vydání:	2010
Předmět:	chemistry.chemical_compound chemistry Silicon Sodium iodide Yield (chemistry) chemistry.chemical_element General Medicine Medicinal chemistry Enol Triethylamine
Zdroj:	ChemInform. 23
ISSN:	0931-7597
DOI:	10.1002/chin.199208245
Popis:	Symmetrical dimethylsilyl bis-enol ethers are obtained in good yield by reaction of ketones with dichlorodimethylsilane in the presence of triethylamine and sodium iodide. Reaction of ketones with N, N - diethylaminodimethylchlorosilane in the presence of triethylamine and sodium iodide followed by subsequent conversions provides a useful synthesis of silicon-functionalized dimethylsilyl enol ethers including unsymmetrical dimethylsilyl bis-enol ethers
Databáze:	OpenAIRE
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