A generalization of the base effect on the diastereoselective synthesis of sulfinic and phosphinic esters

Autor:	Aranzazu Roca, Inmaculada Fernández, Abdelhak Benabra, José L. Espartero, Noureddine Khiar, Ana Alcudia, Felipe Alcudia
Rok vydání:	1999
Předmět:	chemistry.chemical_classification Base (chemistry) chemistry Organic Chemistry Drug Discovery Enantioselective synthesis Organic chemistry Phosphinate Biochemistry
Zdroj:	Tetrahedron Letters. 40:2029-2032
ISSN:	0040-4039
Popis:	Various chiral secondary alcohols have been used to study the dependence of the stereochemical outcome of sulfinate and phosphinate ester synthesis on the nature of the base used to catalyse the reaction. From this study it has been shown that the achiral stereodirecting base effect determined in the DAG methodology is a general behaviour in the asymmetric synthesis of sulfinate and phosphinate esters.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::ba6e20d16c9dc49143d876a6eda0ef7d https://doi.org/10.1016/s0040-4039(99)00171-9 Zobrazit plný text záznamu Full Text from ScienceDirect