Vibrational relaxation of BF3 in the range 182–473 K and in rare-gas mixtures at 295 K
Autor: | Peter Hess, W. Janiesch, R. Ahrens-Botzong, R. Kadibelban |
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Rok vydání: | 1977 |
Předmět: | |
Zdroj: | Chemical Physics Letters. 52:219-223 |
ISSN: | 0009-2614 |
DOI: | 10.1016/0009-2614(77)80527-7 |
Popis: | The vibrational relaxation of pure BF 3 has been studied in the interval 182–473 K using acoustic methods. The rate constant for the self-relaxation of BF 3 shows a minimum around 250 K. This low temperature behavior is discussed in detail. In addition the relaxation of BF 3 in mixtures with D 2 , He, Ne, Ar, Kr, and Xe has been investigated at 295 K by ultrasonic dispersion measurements. |
Databáze: | OpenAIRE |
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