Vibrational relaxation of BF3 in the range 182–473 K and in rare-gas mixtures at 295 K

Autor: Peter Hess, W. Janiesch, R. Ahrens-Botzong, R. Kadibelban
Rok vydání: 1977
Předmět:
Zdroj: Chemical Physics Letters. 52:219-223
ISSN: 0009-2614
DOI: 10.1016/0009-2614(77)80527-7
Popis: The vibrational relaxation of pure BF 3 has been studied in the interval 182–473 K using acoustic methods. The rate constant for the self-relaxation of BF 3 shows a minimum around 250 K. This low temperature behavior is discussed in detail. In addition the relaxation of BF 3 in mixtures with D 2 , He, Ne, Ar, Kr, and Xe has been investigated at 295 K by ultrasonic dispersion measurements.
Databáze: OpenAIRE