A novel two-dimensional framework solid composed of nanosized molybdenum-oxide molecules: synthesis and characterization of [{Gd(H2O)5}4{Mo36(NO)4O108(H2O)16}]·34 H2O

Autor:	Dieter Fenske, Mikhail Yu. Antipin, Fedor M. Dolgushin, N. V. Izarova, Vladimir P. Fedin, Maxim N. Sokolov
Rok vydání:	2005
Předmět:	chemistry.chemical_classification Coordination polymer Stereochemistry General Chemical Engineering chemistry.chemical_element Salt (chemistry) General Chemistry Crystal structure Chemical synthesis chemistry.chemical_compound Crystallography chemistry Molybdenum Polyoxometalate Molecule Hydrate
Zdroj:	Comptes Rendus Chimie. 8:1922-1926
ISSN:	1631-0748
Popis:	Reaction of the ammonium salt of keplerate, [{(MoVI)MoVI5O21(H2O)6}12{MoV2O4CH3COO)}30]42– with Gd(NO3)3 leads to complex transformations with [{Gd(H2O)5}4{Mo36(NO)4O108(H2O)16}]·34 H2O (1) as final product. According to X-ray structural data it contains anions [Mo36(NO)4O108(H2O)16]12–, cross-linked into a neutral 2D-framework by Gd3+ ions. To cite this article: N.V. Izarova et al., C. R. Chimie 8 (2005).
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::ba575b3700da9cdd30b548401eac8cdb https://doi.org/10.1016/j.crci.2005.02.025 Zobrazit plný text záznamu