A novel two-dimensional framework solid composed of nanosized molybdenum-oxide molecules: synthesis and characterization of [{Gd(H2O)5}4{Mo36(NO)4O108(H2O)16}]·34 H2O
Autor: | Dieter Fenske, Mikhail Yu. Antipin, Fedor M. Dolgushin, N. V. Izarova, Vladimir P. Fedin, Maxim N. Sokolov |
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Rok vydání: | 2005 |
Předmět: | |
Zdroj: | Comptes Rendus Chimie. 8:1922-1926 |
ISSN: | 1631-0748 |
Popis: | Reaction of the ammonium salt of keplerate, [{(MoVI)MoVI5O21(H2O)6}12{MoV2O4CH3COO)}30]42– with Gd(NO3)3 leads to complex transformations with [{Gd(H2O)5}4{Mo36(NO)4O108(H2O)16}]·34 H2O (1) as final product. According to X-ray structural data it contains anions [Mo36(NO)4O108(H2O)16]12–, cross-linked into a neutral 2D-framework by Gd3+ ions. To cite this article: N.V. Izarova et al., C. R. Chimie 8 (2005). |
Databáze: | OpenAIRE |
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