Synthesis and Structure of the Copper(II) Chloride Complex with (2-Bromophenyl)thioacetic Acid Morpholide
Autor: | Alexander V. Belyakov, M. N. Krivchun, E. A. Popova, Mikhail L. Petrov |
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Rok vydání: | 2020 |
Předmět: |
Quantum chemical
chemistry.chemical_classification 010405 organic chemistry chemistry.chemical_element General Chemistry 010402 general chemistry 01 natural sciences Copper Chloride 0104 chemical sciences chemistry.chemical_compound chemistry Polymer chemistry Copper(II) chloride medicine Molecule Thioacetic acid Thioamide medicine.drug |
Zdroj: | Russian Journal of General Chemistry. 90:858-862 |
ISSN: | 1608-3350 1070-3632 |
DOI: | 10.1134/s1070363220050163 |
Popis: | The cyclization of (2-bromophenyl)thioacetic acid morpholide to 2-(morpholin-4-yl)-1-benzothiophene in the presence of copper(II) chloride has been found to involve intermediate formation of a complex consisting of two thioamide molecules and one copper cation. The complex has been isolated, and its molecular structure parameters have been determined by quantum chemical calculations. |
Databáze: | OpenAIRE |
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