Synthesis and Structure of the Copper(II) Chloride Complex with (2-Bromophenyl)thioacetic Acid Morpholide

Autor: Alexander V. Belyakov, M. N. Krivchun, E. A. Popova, Mikhail L. Petrov
Rok vydání: 2020
Předmět:
Zdroj: Russian Journal of General Chemistry. 90:858-862
ISSN: 1608-3350
1070-3632
DOI: 10.1134/s1070363220050163
Popis: The cyclization of (2-bromophenyl)thioacetic acid morpholide to 2-(morpholin-4-yl)-1-benzothiophene in the presence of copper(II) chloride has been found to involve intermediate formation of a complex consisting of two thioamide molecules and one copper cation. The complex has been isolated, and its molecular structure parameters have been determined by quantum chemical calculations.
Databáze: OpenAIRE
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