Synthesis of a multicyclic polymer with hyperbranched structure by click polymerization of an AB2 cyclic macromonomer
| Autor: | Cai-Yuan Pan, Chao Liu, Chun-Yan Hong, Hua-long Zhang, Wen Xu |
|---|---|
| Rok vydání: | 2021 |
| Předmět: |
chemistry.chemical_classification
Polymers and Plastics Organic Chemistry Radical polymerization Bioengineering 02 engineering and technology Polymer 010402 general chemistry 021001 nanoscience & nanotechnology Macromonomer 01 natural sciences Biochemistry 0104 chemical sciences Styrene chemistry.chemical_compound chemistry Polymerization Polymer chemistry Click chemistry Azide Polystyrene 0210 nano-technology |
| Zdroj: | Polymer Chemistry. 12:759-765 |
| ISSN: | 1759-9962 1759-9954 |
| DOI: | 10.1039/d0py01604g |
| Popis: | A multicyclic polymer with a hyperbranched structure was successfully synthesized. A tailored initiator containing a protected alkynyl group was prepared and used to initiate the atom transfer radical polymerization (ATRP) of styrene. By the combination of a click reaction, a UV-induced coupling reaction and post-modification, an AB2 type cyclic polystyrene with a protected alkynyl group and two azide groups was obtained, and after deprotection, the clickable cyclic polymer was used as a macromonomer to prepare a multicyclic polymer with a hyperbranched structure by click polymerization via the AB2 strategy. Gel permeation chromatography (GPC) results showed that the obtained hyperbranched multicyclic polymer contained 47 cyclic units on average. |
| Databáze: | OpenAIRE |
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