Ni[TCNE]2·zCH2Cl2 (Tc=13 K) and VxNi1−x[TCNE]y·zCH2Cl2 solid solution room temperature magnets

Autor:	Elaine B. Vickers, Andrew Senesi, Joel S. Miller
Rok vydání:	2004
Předmět:	Inorganic Chemistry Nickel chemistry.chemical_compound Condensed matter physics chemistry Magnet Materials Chemistry Analytical chemistry chemistry.chemical_element Vanadium Physical and Theoretical Chemistry Tetracyanoethylene Solid solution
Zdroj:	Inorganica Chimica Acta. 357:3889-3894
ISSN:	0020-1693
DOI:	10.1016/j.ica.2004.04.030
Popis:	Magnetically ordered Ni[TCNE]2 · zCH2Cl2 (Tc = 13 K) is reported for the first time from the reaction of Ni(CO)4 with tetracyanoethylene (TCNE). A family of new solid solution room temperature magnets of VxNi1 − x[TCNE]y · zCH2Cl2 (0 ≤ x 0; however, the magnitude of M increases with x, as does the broadness of the peaks in the χ′(T) and χ″(T) ac susceptibilities. Hence, the magnetic properties of the room temperature V[TCNE]y · zCH2Cl2 magnet can be finely tuned via synthetic chemistry methodology, making this material more amenable in future technologies.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::ba4064247e2bd5da38d552bda0900c0b https://doi.org/10.1016/j.ica.2004.04.030 Zobrazit plný text záznamu Full Text from ScienceDirect