Penultimate effects in the copolymerization of maleic anhydride with electron-rich styrene derivatives
| Autor: | Niels ten Brummelhuis, Marvin Björn Stutz |
|---|---|
| Rok vydání: | 2016 |
| Předmět: |
chemistry.chemical_classification
Polymers and Plastics Organic Chemistry Maleic anhydride 02 engineering and technology Raft Polymer 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences 0104 chemical sciences Styrene chemistry.chemical_compound Monomer chemistry Polymer chemistry Materials Chemistry Copolymer Organic chemistry 0210 nano-technology |
| Zdroj: | Journal of Polymer Science Part A: Polymer Chemistry. 54:2932-2939 |
| ISSN: | 0887-624X |
| Popis: | The (controlled) free-radical copolymerization of maleic anhydride and styrene or derivatives thereof is often thought to provide nearly perfect alternating copolymers. Here, the RAFT copolymerization of electron-rich styrene derivatives with maleic anhydride is reported. This copolymerization shows distinct penultimate effects, resulting in polymers with increased incorporation of styrene monomers, that is, where a tendency toward periodic (S-S-MA) copolymers exists. This work could be a first step towards periodic copolymers based on maleic anhydride and styrene derivatives. © 2016 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2016, 54, 2932–2939 |
| Databáze: | OpenAIRE |
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