Skeletal isomerization of n-butylenes to isobutylene on zeolites

Autor:	John Hazen, Chi-Lin O'Young, Regis J. Pellet, James E. Browne, Alison E. Hadowanetz
Rok vydání:	1997
Předmět:	Isobutylene chemistry.chemical_classification chemistry.chemical_compound Olefin fiber chemistry Organic chemistry Angstrom Zeolite Isomerization Alkyl General Environmental Science Catalysis
Zdroj:	Zeolites. 18:233-234
ISSN:	0144-2449
DOI:	10.1016/s0144-2449(97)83984-x
Popis:	The conversion of normal olefins such as n-butylenes can be converted to branched olefin species such as isobutylene by skeletal isomerization over zeolite-based catalysts having pore sizes of at least about 4.5 Angstroms and a pore structure characterized by intersecting 10-MR and 8 MR channels. The zeolite-based catalysts have sufficient acidity to catalyze the skeletal isomerization of normal olefins. The catalysts can be used to produce isoolefins for reaction with alcohols in integrated processes to produce alkyl tertiary alkyl ethers such as MTBE.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::ba0ef70543ed7d01c917ced8de9b74d4 https://doi.org/10.1016/s0144-2449(97)83984-x Zobrazit plný text záznamu Full Text from ScienceDirect