Dipole forbidden vibrational modes for NO and CO on Cu observed in the far IR
| Autor: | Ph. Dumas, F. M. Hoffmann, M. Suhren, Carol J. Hirschmugl, Yves J. Chabal, Gwyn P. Williams |
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| Rok vydání: | 1993 |
| Předmět: |
Range (particle radiation)
Radiation Scattering Chemistry Condensed Matter Physics Atomic and Molecular Physics and Optics Spectral line Electronic Optical and Magnetic Materials Dipole Molecular vibration Absorption (logic) Physical and Theoretical Chemistry Atomic physics Broadband absorption Spectroscopy Intensity (heat transfer) |
| Zdroj: | Journal of Electron Spectroscopy and Related Phenomena. :67-73 |
| ISSN: | 0368-2048 |
| Popis: | IRRAS spectra of NO/Cu(111) and ({radical}3 {times} {radical}3)R30{degrees} coverage of CO/Cu(111) in the range 3000--180 cm{sup {minus}1} show both the adsorbate internal modes and features assigned to the hindered rotational modes. These dipole-forbidden features are characterized by asymmetric (mostly negative) absorption lineshapes and are accompanied by a change in broadband absorption. The shape and intensity of this broadband absorption is well accounted for by a scattering model. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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