Autor: I. Smirani, A. Graja, A. Brau, J.-P. Farges, R. Lipiec
Rok vydání: 2001
Předmět:
Zdroj: Journal of Materials Science. 36:1227-1230
ISSN: 0022-2461
DOI: 10.1023/a:1004898329344
Popis: We present new results on organic semiconductive and metallic composites obtained by direct solid-solid charge-transfer (CT) reaction. By this method, samples of arbitrarily large size are readily achievable. In the present study, we consider composites formed from the reaction between the following pairs of donors and acceptors: TTF and iodine, BEDT-TTF and TCNQ, BEDT-TTF and TCNE, BEDT-TTF and AuI as well as BEDT-TTF and AuI3. Most of the composites show semiconducting properties only. Two of them, however, (BEDT-TTF)/(AuI) and (BEDT-TTF)2/(AuI3), exhibit a metallic behavior.
Databáze: OpenAIRE