Asymmetric transfer hydrogenation over rhodium catalysts in the presence of chiral diamine

Autor:	L. O. Nindakova, V. D. Goryunova
Rok vydání:	2020
Předmět:	chemistry.chemical_element Transfer hydrogenation Medicinal chemistry Rhodium Catalysis Chiral diamine Metal chemistry.chemical_compound chemistry visual_art Diamine visual_art.visual_art_medium Formate Acetophenone
Zdroj:	INTERNATIONAL CONFERENCE ON PHYSICS AND CHEMISTRY OF COMBUSTION AND PROCESSES IN EXTREME ENVIRONMENTS (COMPHYSCHEM’20-21) and VI INTERNATIONAL SUMMER SCHOOL “MODERN QUANTUM CHEMISTRY METHODS IN APPLICATIONS”.
ISSN:	0094-243X
DOI:	10.1063/5.0033044
Popis:	The reactions of hydrogen transfer from 2-propanol on acetophenone and keto acid esters (methyl pyruvate, methyl benzoyl formate) in the presence of the system {[Rh(COD)Cl]2–(R,R)-2–base}, where ((R,R)-2 is N1,N2−bis (thiophen-2-yl-methyl)cyclohexane-1,2-diamine), was studied. Hydrogen transfer proceeds both on metal complexes of rhodium(I) with diamine (R,R)-2 and on chiral modified RhNPs.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::b9e41659d48726f79e81e96c7554bf3b https://doi.org/10.1063/5.0033044 Zobrazit plný text záznamu