Polarographic investigation of the mobility of halogen atoms in halogen-substituted components of nucleic acids

Autor:	V. P. Kadysh, L. N. Rumyantseva, Yu. L. Kaminskii, Ya. P. Stradyn, V. L. Efimova
Rok vydání:	1992
Předmět:	inorganic chemicals Polarography Bromine chemistry Organic Chemistry Atom Halogen Inorganic chemistry Nucleic acid Molecule chemistry.chemical_element Electrochemistry Iodine
Zdroj:	Chemistry of Heterocyclic Compounds. 28:1198-1202
ISSN:	1573-8353 0009-3122
DOI:	10.1007/bf00529588
Popis:	In order to establish quantitatively the reducibility of halogen-substituted components of nucleic acids, the half-wave potentials (E1/2) of their electrochemical reduction have been determined. The electrochemical reduction of all compounds takes place in the interval from −0.5 to −1.8 V and consists in the splitting off of the halogen atom (iodine, bromine) from the given molecule. The iodine derivatives are reduced much more readily (500–800 mV) than the bromine derivatives.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::b9dfa84043663bda81abff04904c4c16 https://doi.org/10.1007/bf00529588 Zobrazit plný text záznamu Full text from SpringerLink