Radical Addition to Levoglucosenone, Synthesis of Anhydrosugar Herbicide Analogues

Autor:	Regine Blattner, Dennis M. Page
Rok vydání:	1994
Předmět:	chemistry.chemical_classification Addition reaction Bicyclic molecule Chemistry Organic Chemistry Free-radical reaction Alkyl radicals Biochemistry chemistry.chemical_compound Aldose Chemical reduction Organic chemistry Methylene Derivative (chemistry)
Zdroj:	Journal of Carbohydrate Chemistry. 13:27-36
ISSN:	1532-2327 0732-8303
DOI:	10.1080/07328309408009175
Popis:	Addition of alkyl radicals to levoglucosenone (5) gave 4-C-alkyl-1,6-anhydro-3,4-dideoxy-β-d-erythro-hexopyranos-2-uloses 7 in moderate to good yields. The 4-C-phenyl ethyl derivative 7a was converted by reduction and methylation to the methylene isoster 3 of the powerful herbicide 1.
Databáze:	OpenAIRE
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