Anionic and cationic photodissociation of the chloroform molecule excited in the vicinity of the Cl 1s edge

Autor:	R. L. Cavasso-Filho, Wayne C. Stolte, A. C. F. Santos, G. G. B. de Souza, Alexsandre F. Lago, Alfred S. Schlachter
Rok vydání:	2012
Předmět:	Chemistry Photodissociation Cationic polymerization General Physics and Astronomy Photoionization Photochemistry Dissociation (chemistry) Ion Excited state Physics::Atomic and Molecular Clusters Molecule Physics::Chemical Physics Physical and Theoretical Chemistry Time-of-flight mass spectrometry
Zdroj:	Chemical Physics Letters. 543:34-40
ISSN:	0009-2614
Popis:	The anionic and cationic photodissociation from deep-core excited chloroform molecule has been investigated in the vicinity of the Cl 1s excitation edge. We used synchrotron radiation, time of flight mass spectrometry and ion yield spectroscopy. From our partial anion yield results we were able to observe for the first time the formation of the following anionic species: Cl − , H − and C − . From our TOF spectra we determined the cations produced in order to discuss the photoionization and dissociation dynamics for this core excited molecule. It provided evidences of the complex dynamics of negative and positive ion formation from CHCl 3 upon photo-excitation in the vicinity of the Cl 1s edge.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::b99a119007b57385cf575afdea6278cc https://doi.org/10.1016/j.cplett.2012.06.040 Zobrazit plný text záznamu Full Text from ScienceDirect