Importance of axial ligand in meso-tetraphenylporphinatoiron(III) promoted NO and OO bonds cleavages

Autor:	Seiichi Fujiwara, Toshikazu Takata, Shigeru Oae, Ken Fujimori
Rok vydání:	1986
Předmět:	Chemistry Ligand Stereochemistry Organic Chemistry Biochemistry Medicinal chemistry Amine oxide chemistry.chemical_compound Cumene hydroperoxide Enzyme model Drug Discovery Imidazole Deoxygenation Bond cleavage Demethylation
Zdroj:	Tetrahedron Letters. 27:581-584
ISSN:	0040-4039
Popis:	Amines, especially imidazole, were found to be essential in the meso-tetraphenylporphinatoiron (III) promoted demethylation of N, N-dimethylaniline N-oxide through the Polonovski type reaction and in the cumene hydroperoxide dependent oxidative demethylation of N, N-dimethylaniline in dichloromethane. When benzenethoil was used instead of these amines, deoxygenation of N, N-dimethylaniline N-oxide took place very readily
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::b979d0d699e9588b708c1d63580d7343 https://doi.org/10.1016/s0040-4039(00)84046-0 Zobrazit plný text záznamu