Synthesis and structure of a dinuclear cobalt carbonyl derivative containing methyldithioformate as a five-electron donor ligand

Autor:	Gábor Szalontai, Sándor Vastag, Giuliana Gervasio, László Markó
Rok vydání:	1997
Předmět:	Inorganic Chemistry chemistry.chemical_compound chemistry Cobalt carbonyl Stereochemistry Ligand Organic Chemistry Polymer chemistry Materials Chemistry Electron donor Physical and Theoretical Chemistry Dicobalt octacarbonyl Biochemistry
Zdroj:	Journal of Organometallic Chemistry. 533:187-191
ISSN:	0022-328X
DOI:	10.1016/s0022-328x(96)06813-1
Popis:	Dicobalt octacarbonyl reacts with an excess of (MeSCS2)2 to form several sulfur-containing cobalt carbonyl derivatives; on addition of PPh3, the complex Co2(CO)2(PPh3)2(1,3-η-S2CSMe)(μ-1,2-η-SCSMe) (1) could be isolated from the reaction mixture. The structure of complex 1 was determined by X-ray crystallography; it contains a methyl dithioformate ligand in which the ligand donates five electrons to the cluster and the CS group is bound perpendicular to the Co2 core.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::b96d0de1dcd0bbe986f1da11ba480b52 https://doi.org/10.1016/s0022-328x(96)06813-1 Zobrazit plný text záznamu Full Text from ScienceDirect