The relevance of the nuclearity of the metal in the cocyclization of α, ω-diynes and nitriles catalyzed by mesitylene solvated cobalt atoms; preliminary EPR studies
| Autor: | Sergio Bertozzi, Paolo Pertici, Arturo Colligiani, Piero Salvadori, Giovanni Vitulli, Raffaello Lazzaroni |
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| Rok vydání: | 1988 |
| Předmět: |
inorganic chemicals
Nitrile Organic Chemistry chemistry.chemical_element Photochemistry Biochemistry Catalysis law.invention Inorganic Chemistry Metal chemistry.chemical_compound chemistry law visual_art Polymer chemistry Materials Chemistry visual_art.visual_art_medium Physical and Theoretical Chemistry Aliphatic compound Electron paramagnetic resonance Acetonitrile Mesitylene Cobalt |
| Zdroj: | Journal of Organometallic Chemistry. 353:C35-C38 |
| ISSN: | 0022-328X |
| Popis: | The clustering when mesitylene-solvated cobalt atoms are allowed to warm from the cocondensation temperature, affords cobalt compounds of both low and high nuclearity which have different catalytic properties in the synthesis of pyridines from α, ω-dialkynes and nitriles. |
| Databáze: | OpenAIRE |
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