ChemInform Abstract: Secoorthosiphols A-C: Three Highly Oxygenated Secoisopimarane-Type Diterpenes from Orthosiphon stamineus
Autor: | Suresh Awale, Kazuhiko Taira, Seikichi Shimoji, Shigetoshi Kadota, Yasuhiro Tezuka |
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Rok vydání: | 2010 |
Předmět: | |
Zdroj: | ChemInform. 33 |
ISSN: | 1522-2667 0931-7597 |
Popis: | Three new highly oxygenated 2,3-secoisopimarane-type diterpenes, named secoorthosiphols A (1), B (2) and C (3), have been isolated as extremely minor constituents from the aerial parts of the Orthosiphon stamineus from Okinawa. A unique unprecedented structural feature of such a ring A opened system in newly isolated compounds was encountered for the first time in isopimarane-type diterpenes. Secoorthosiphol C (3) represents the first example of a biogenetically unique and unconventional secoisopimarane-type diterpene having a cyano group. |
Databáze: | OpenAIRE |
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