Selective hydroxylation of cyclohexene over Fe-bipyridine complexes encapsulated into Y-type zeolite under environment-friendly conditions

Autor:	Chiharu Fujita, Syuhei Yamaguchi, Yasutake Teraoka, Tomohiro Fukura, Hidenori Yahiro, Keiko Takiguchi, Maiko Nishibori
Rok vydání:	2015
Předmět:	Inorganic chemistry Cyclohexene General Chemistry Catalysis Hydroxylation Solvent chemistry.chemical_compound Bipyridine chemistry Polymer chemistry Zeolite Selectivity Hydrogen peroxide
Zdroj:	Catalysis Today. 242:261-267
ISSN:	0920-5861
DOI:	10.1016/j.cattod.2014.07.038
Popis:	Fe-bipyridine complexes encapsulated into Na-Y ([Fe(bpy)3]2+@Y) were prepared and their catalytic activities for oxidation of cyclohexene with hydrogen peroxide in CH3CN and H2O solvents were investigated. The prepared [Fe(bpy)3]2+@Y was characterized by several methods and it was found that slightly distorted or compressed [Fe(bpy)3]2+ ions were formed within supercages of Y-type zeolite. [Fe(bpy)3]2+@Y catalyst exhibited both higher activity and higher selectivity to 2-cyclohexen-1-ol in water solvent than another Fe catalysts. In addition, the selective hydroxylation of cyclohexene to 2-cyclohexen-1-ol with molecular oxygen was successfully achieved for [Fe(bpy)3]2+@Y catalyst.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::b92c6d303e8367779ce65da3e6da57ac https://doi.org/10.1016/j.cattod.2014.07.038 Zobrazit plný text záznamu Full Text from ScienceDirect