Communication—Electrochemical Reduction of CO2 and N2 into Urea at ZIF-8 Cathode

Autor:	Jiongliang Yuan, Zhaotao Liu, Lingjia Ma, Zefeng Feng, Kunye Zhu
Rok vydání:	2023
Předmět:	Renewable Energy Sustainability and the Environment Materials Chemistry Electrochemistry Condensed Matter Physics Surfaces Coatings and Films Electronic Optical and Magnetic Materials
Zdroj:	Journal of The Electrochemical Society. 170:043503
ISSN:	1945-7111 0013-4651
DOI:	10.1149/1945-7111/acc97d
Popis:	The synthesis of urea has been usually performed in two steps under high temperature and high pressure with huge energy consumption. In this communication, we proposed a one-step electrocatalytic synthesis of urea under ambient condition using ZIF-8 as the catalyst and CO2 and N2 as the feedstocks. At an applied voltage of −0.10 V vs RHE, the strongest Raman peak of the C-N intermediate was observed, thus the highest rate of urea yield of 5.45 mmol h−1 g−1 was achieved, with a corresponding Faradaic efficiency of 22.03%.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::b91909d22641207e4a634576f8f6ebb1 https://doi.org/10.1149/1945-7111/acc97d Zobrazit plný text záznamu