Further studies of [Ni4(DAniDANy)4] (DAniDANy2−=N,N’-bis-p-anisyl-2,7-diamido-1,8-naphthyridine) and its one-electron oxidation product: Metal-metal sigma bonding in Ni49+ complex

Autor:	Chih-Hsien Chien, Isiah Po-Chun Liu, Shie-Ming Peng, Gin-Chen Huang, Gene-Hsiang Lee, Jau-Huei Kuo, Shao-An Hua
Rok vydání:	2012
Předmět:	Molecular switch Crystal Molecular wire Crystallography Chemistry General Chemical Engineering Product (mathematics) Inorganic chemistry Sigma Metal metal General Chemistry Electron Antibonding molecular orbital
Zdroj:	Comptes Rendus Chimie. 15:159-162
ISSN:	1631-0748
DOI:	10.1016/j.crci.2011.05.002
Popis:	The linear tetranickel strings, [Ni4(DAniDANy)4] (1), and its one-electron oxidation product, [Ni4(DAniDANy)4](PF6) (2), have been synthesized and studied extensively (DAniDANy2− = N,N’-bis-p-anisyl-2,7-diamido-1,8-naphthyridine). Crystal structural analyses and DFT calculations suggest that the chemical oxidation of 1 involves removal of an electron from the σ* antibonding orbital, which results in the formation of Ni-Ni bonds in 2.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::b90f5caafaa4913bf401d800a3c99ee4 https://doi.org/10.1016/j.crci.2011.05.002 Zobrazit plný text záznamu