Synchrotron X-Ray Study of Novel Crystalline-BPhases in Heptyloxybenzylidene-Heptylaniline (7O.7)

Autor: J. Collett, J. D. Litster, Robert J. Birgeneau, L. B. Sorensen, Jens Aage Als-Nielsen, Peter S. Pershan
Rok vydání: 1982
Předmět:
Zdroj: Physical Review Letters. 49:553-556
ISSN: 0031-9007
DOI: 10.1103/physrevlett.49.553
Popis: This paper reports an x-ray diffraction study of structures and restacking transitions within the $B$ phases of heptyloxybenzylidene-heptylaniline. The system evolves from a hexagonal close-packed structure, through intermediate orthorhombic and monoclinic phases, to a simple hexagonal structure. The monoclinic phase has a temperature-dependent shear which transforms the system from orthorhombic to hexagonal. The latter three phases exhibit a single-$\stackrel{\ensuremath{\rightarrow}}{\mathrm{q}}$ sinusoidal modulation of the molecular layers.
Databáze: OpenAIRE