Ruthenium-catalyzed hydrosilylation of alkynes by using hydrooligosilanes without Si–Si bond cleavage

Autor:	Ken-ichiro Kanno, Yumi Aikawa, Soichiro Kyushin
Rok vydání:	2020
Předmět:	010405 organic chemistry Hydrosilylation Organic Chemistry chemistry.chemical_element 010402 general chemistry 01 natural sciences Biochemistry 0104 chemical sciences Catalysis Ruthenium chemistry.chemical_compound chemistry Drug Discovery Polymer chemistry Bond cleavage
Zdroj:	Tetrahedron Letters. 61:152274
ISSN:	0040-4039
Popis:	Ruthenium-catalyzed hydrosilylation of alkynes was applied to hydrooligosilanes to furnish alkenyloligosilanes without Si–Si bond cleavage in good yields. The (E)- and α-adducts were obtained regio- and stereoselectively by using RuHCl(CO)(PPh3)3 and [Cp*RuCl2]n as catalysts, respectively.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::b904f142277c7c74c1c565a6b5b1af1b https://doi.org/10.1016/j.tetlet.2020.152274 Zobrazit plný text záznamu Full Text from ScienceDirect