Intermediate State in Monomolecular Films: A Re‐evaluation

Autor:	R. J. Demchak, D.A. Cadenhead
Rok vydání:	1968
Předmět:	Crystallography chemistry.chemical_compound Aqueous solution Chemistry Amphiphile Glycerol General Physics and Astronomy Intermediate state Organic chemistry Molecule Physical and Theoretical Chemistry Atmospheric temperature range
Zdroj:	The Journal of Chemical Physics. 49:1372-1375
ISSN:	1089-7690 0021-9606
Popis:	The monomolecular film characteristics of 4‐amino‐p‐terphenyl have been determined over the temperature range 0°–31°C on a variety of aqueous substrates: alkaline (pH 10), alkaline (pH 10) with 2M NaCl and with 30 wt.% glycerol. No indication of an intermediate state was found. From these results and others already reported, it was concluded that the Kirkwood theory concerning this state is not correct, and that the exhibition of such a transition region is an inherent property of the internal motions of the paraffinic chains possessed by many amphipathic molecules.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::b8f7050c72c8fe32489a381986dc80b0 https://doi.org/10.1063/1.1670233 Zobrazit plný text záznamu