Platinum(II) and palladium(II) complexes with substituted pyrimidines

Autor:	S. M. Zakeeruddin, Badar Taqui Khan
Rok vydání:	1991
Předmět:	Denticity Chemistry Inorganic chemistry Metals and Alloys chemistry.chemical_element Catalysis Inorganic Chemistry Metal chemistry.chemical_compound visual_art Polymer chemistry Materials Chemistry visual_art.visual_art_medium Chelation Isocytosine Platinum Organometallic chemistry Palladium
Zdroj:	Transition Metal Chemistry. 16:119-121
ISSN:	1572-901X 0340-4285
DOI:	10.1007/bf01127885
Popis:	Platinum(II) and Palladium(II) complexes with 2-mercaptopyrimidine, 2-thiocytosine (4-aminopyrimidine 2-thione), and isocytosine (2-amino-4-hydroxy pyrimidine) were prepared and characterised by elemental analysis, conductivity data, i.r.,1H n.m.r. and13C n.M.r. spectral studies. 2-Mercaptopyrimidine and 2-thiocytosine are coordinated to the metal ion through N(3) and C2S, thus forming a four-membered chelate ring. Isocytosine acts as a monodentate ligand and coordinates to the metal ion through N(1). All the complexes are non-electrolytes.
Databáze:	OpenAIRE
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