Photochemical Grafting and Patterning of Metallic Surfaces by Organic Layers Derived from Acetonitrile
| Autor: | Fetah I. Podvorica, Jean Pinson, Géraldine Hallais, Avni Berisha, Frédéric Kanoufi, Catherine Combellas |
|---|---|
| Rok vydání: | 2011 |
| Předmět: |
Materials science
General Chemical Engineering chemistry.chemical_element General Chemistry Photochemistry Copper Solvent Metal chemistry.chemical_compound chemistry Covalent bond visual_art Photografting Materials Chemistry visual_art.visual_art_medium Surface modification Acetonitrile Layer (electronics) |
| Zdroj: | Chemistry of Materials. 23:3449-3459 |
| ISSN: | 1520-5002 0897-4756 |
| Popis: | Metallic substrates are modified by a polymeric layer obtained under photochemical irradiation of acetonitrile. The reaction involves a photogenerated radical and leads to the covalent bonding of the organic layer to the metal. Different characterization techniques allow to unravel the structure of the layer: Substrate-CH2-CH-(NH2)[-CH2-CH-(NH2)-]n-[CH2-C(═O)]m. A mechanism is discussed that accounts for the formation of the layer. The method is quite easy to implement, it only necessitates a UV lamp and a very common solvent. Photografting is well suited to pattern surfaces with polymeric layers by irradiation through a mask, and finally, the patterning of copper at the micrometer scale is described as a proof of concept. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|