Hexamethonium bis(tribromide) (HMBTB) a recyclable and high bromine containing reagent

Autor:	Bhisma K. Patel, Bishal Bhuyan, Siddhartha Sankar Dhar, Bappi Paul, Debraj Dhar Purkayastha
Rok vydání:	2015
Předmět:	Bromine Organic Chemistry Halogenation chemistry.chemical_element Regioselectivity Biochemistry chemistry.chemical_compound chemistry Reagent Drug Discovery Polymer chemistry Hexamethonium Bromide Hexamethonium Tribromide
Zdroj:	Tetrahedron Letters. 56:5646-5650
ISSN:	0040-4039
DOI:	10.1016/j.tetlet.2015.08.063
Popis:	A recyclable and high bromine containing di-(tribromide) reagent, hexamethonium bis(tribromide) (HMBTB) has been synthesized and utilized for the bromination of various organic substrates. The spent reagent hexamethonium bromide (HMB) can be effectively recycled by regenerating and reusing it without significant loss of activity. The crystalline and stable bis(tribromide) is an effective storehouse of very high percentage of active bromine requiring just half an equivalent of it for complete bromination. Both the Br3− moieties in HMBTB are nearly linear with Br–Br–Br angle of 179.55°.
Databáze:	OpenAIRE
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