A water-stable Zn (II) coordination polymer as fluorescent sensor for selective and sensitive detection of antibiotics and Fe3+
| Autor: | Wen-Wen Dong, Hui-Min Han, Yu Xiaoyan, Dongsheng Li, Jun Zhao |
|---|---|
| Rok vydání: | 2021 |
| Předmět: |
chemistry.chemical_classification
Quenching (fluorescence) Coordination polymer Aqueous two-phase system 02 engineering and technology Polymer 010402 general chemistry 021001 nanoscience & nanotechnology Condensed Matter Physics 01 natural sciences Combinatorial chemistry Fluorescence 0104 chemical sciences Electronic Optical and Magnetic Materials Inorganic Chemistry chemistry.chemical_compound chemistry Materials Chemistry Ceramics and Composites Physical and Theoretical Chemistry Absorption (chemistry) 0210 nano-technology Selectivity Luminescence |
| Zdroj: | Journal of Solid State Chemistry. 296:122032 |
| ISSN: | 0022-4596 |
| Popis: | A novel 3D Zn (II)-based coordination polymer, [ZnL(H2O)2] (complex 1) (H2L = 2,5-di(1H-1,2,4-triazol-1-yl)terephthalic) with some active uncoordinated carboxylic groups, exhibiting excellent luminescence and good stability in water, harsh acidic and basic conditions (pH = 2-12). 1 can act as a promising dual functional sensor for detecting and recognizing NFs (nitrofurazone, NZF; nitrofurantoin, NFT) and Fe3+ ions through fluorescence quenching with highly selectivity and sensitivity in aqueous phase. Besides, the probable mechanisms of the quenching effects are attributed to a competitive absorption mechanism between 1 and analytes. The present work contributes to the development of coordination polymers research, specifically in the application as biological and environmental fluorescent sensor. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|
Full Text from ScienceDirect