The thermochemistry of organo-phosphorus compounds
Autor: | C. T. Mortimer |
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Rok vydání: | 1961 |
Předmět: | |
Zdroj: | Pure and Applied Chemistry. 2:71-76 |
ISSN: | 1365-3075 0033-4545 |
Popis: | After the combustions, the phosphoric acid was, in fact, in aqueous solution, so that a correction for the heat of solution was necessary. These combustions were made in a static bomb, and as a result the concentration of phosphoric acid probably varied considerably in different parts of the bomb, leading to the comparatively large error of ±O·l per cent, associated with the heats of combustion. This error could be reduced very considerably by using a rotating bomb technique. A number of organo-phosphorus compounds undergo reactions which can be studied conveniently in a simple reaction calorimeter. An example |
Databáze: | OpenAIRE |
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