The thermochemistry of organo-phosphorus compounds

Autor:	C. T. Mortimer
Rok vydání:	1961
Předmět:	chemistry.chemical_compound Aqueous solution chemistry Reaction calorimeter General Chemical Engineering Phosphorus Inorganic chemistry Thermochemistry chemistry.chemical_element General Chemistry Combustion Phosphoric acid Enthalpy change of solution
Zdroj:	Pure and Applied Chemistry. 2:71-76
ISSN:	1365-3075 0033-4545
Popis:	After the combustions, the phosphoric acid was, in fact, in aqueous solution, so that a correction for the heat of solution was necessary. These combustions were made in a static bomb, and as a result the concentration of phosphoric acid probably varied considerably in different parts of the bomb, leading to the comparatively large error of ±O·l per cent, associated with the heats of combustion. This error could be reduced very considerably by using a rotating bomb technique. A number of organo-phosphorus compounds undergo reactions which can be studied conveniently in a simple reaction calorimeter. An example
Databáze:	OpenAIRE
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