Crippling the C70 fullerene: non-classical C68Cl26(OH)2 and C68Cl25(OH)3 with three heptagons and only fused pentagons via chlorination-promoted skeletal transformations

Autor:	Victor A. Brotsman, Ilya N. Ioffe, Sergey I. Troyanov
Rok vydání:	2022
Předmět:	Materials Chemistry Metals and Alloys Ceramics and Composites General Chemistry Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials
Zdroj:	Chemical Communications. 58:6918-6921
ISSN:	1364-548X 1359-7345
DOI:	10.1039/d2cc01719a
Popis:	High-temperature chlorination of C70 with SbCl5 promotes a five-step skeletal transformation that gives partially hydrolyzed C68Cl28 with an unprecedented carbon cage featuring three heptagons and 15 pentagons arranged in fused pairs and triples.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::b8e55bb9f7b5390487b938658d530213 https://doi.org/10.1039/d2cc01719a Zobrazit plný text záznamu