| Autor: |
P. Mohanapriya, David McNulty, M.K. Raihana, S. Esakki Muthu, Jhelai Sahadevan, N. Padmanathan, V. Eswaramoorthi |
| Rok vydání: |
2021 |
| Předmět: |
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| Zdroj: |
Electrochimica Acta. 391:138903 |
| ISSN: |
0013-4686 |
| Popis: |
Nickel Phosphate (Ni20[(OH)12(H2O)6][(HPO4)8(PO4)4]•12H2O) – VSB-5 nano/micro rods composite with reduced graphene oxide (rGO) was successfully synthesized using a Polyvinyl Pyrrolidone (PVP) aided hydrothermal technique and applied as a battery-type cathode for supercapatteries. The uniform meso/microporous structure provides more electro-active sites for surface redox reaction and nano-paths for electrolyte ion diffusion which can significantly improve the device performance. From the electrochemical analysis, it was found that VSB-5/rGO exhibited a specific capacity of 117.3 mAh g−1 (1056.1 F g−1) which was noticeably higher than the pristine VSB-5 (60.7 mAh g−1) at 5 mA cm−2. These excellent electrochemical performances may be due to rGO modification and well-defined nano/micro rods. Furthermore, supercapatteries were fabricated by pairing a commercially available activated carbon (AC) electrode with VSB-5/rGO as a positrode. The fabricated cell was tested and showed a high specific capacity of 86.8 mAh g−1 (208.4 F g−1) with 88% capacity retention after 5000 cycles. Finally, the assembled supercapattery delivered a maximum specific energy of 80.5 Wh kg−1 at a power output of 2216.5 W kg−1. In comparison with a pristine VSB-5 based device, the AC/VSB-5/rGO device shows remarkable electrochemical performance, demonstrating that VSB-5/rGO is a promising, new electrode material for high performance supercapatteries. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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