Obsevations on the cleavage of the bismuth–carbon bond in BiVcompounds: a new arylation reaction

Autor:	William B. Motherwell, David J. Lester, Derek H. R. Barton, M. Teresa Barros Papoula
Rok vydání:	1980
Předmět:	inorganic chemicals Allylic rearrangement Aryl food and beverages chemistry.chemical_element Cleavage (embryo) Combinatorial chemistry Bismuth chemistry.chemical_compound chemistry Deuterium Reagent Molecular Medicine Selectivity Carbon
Zdroj:	J. Chem. Soc., Chem. Commun.. :246-247
ISSN:	0022-4936
DOI:	10.1039/c39800000246
Popis:	Further examples of the selectivity of pentavalent trianyl-organobismuth oxidants are presented; deuterium labelling studies have established that the mechanism of oxidation of allylic alcohols by these reagents involves, to some extent, cleavage of the bismuth–aryl bond; several reactions involving the synthetically useful transfer of an aryl group from bismuth to nitrogen and to carbon are described.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::b8d6abb5aaefc7e23f22ef5e9aa3e85e https://doi.org/10.1039/c39800000246 Zobrazit plný text záznamu