The standard Gibbs free energy of formation of lithium manganese oxides at the temperatures of (680, 740 and 800) K
| Autor: | A. Kozłowska-Róg, W. Kucza, G. Róg |
|---|---|
| Rok vydání: | 2004 |
| Předmět: |
Electrolytic cell
Inorganic chemistry Spinel Intercalation (chemistry) chemistry.chemical_element engineering.material Atomic and Molecular Physics and Optics Gibbs free energy chemistry.chemical_compound symbols.namesake Standard Gibbs free energy of formation chemistry Galvanic cell engineering symbols Physical chemistry General Materials Science Lithium Lithium oxide Physical and Theoretical Chemistry |
| Zdroj: | The Journal of Chemical Thermodynamics. 36:473-476 |
| ISSN: | 0021-9614 |
| DOI: | 10.1016/j.jct.2004.02.009 |
| Popis: | The standard Gibbs free energy of formation of LiMnO 2 and LiMn 2 O 4 at the temperatures of (680, 740 and 800) K has been determined with the help of the solid-state galvanic cells involving lithium–β-alumina electrolyte. The equilibrium electrical potentials of cathode containing Li x Mn 2 O 4 spinel, in the composition ranges 0⩽ x ⩽1 and 1⩽ x ⩽2, vs . metallic lithium in the reversible intercalation galvanic cell have been calculated. The existence of two-voltage plateaus which appeared during charging and discharging processes in reversible intercalation of lithium into Li x Mn 2 O 4 spinel, has been discussed. |
| Databáze: | OpenAIRE |
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