Transition Metal Complexes Containing Ligands of Pharmacological Interest

Autor:	D. Craciunescu, A. H. I. Ben-Bassat
Rok vydání:	2010
Předmět:	chemistry.chemical_compound chemistry Nicotinamide Transition metal Stereochemistry Ligand Pyridine chemistry.chemical_element General Chemistry Medicinal chemistry Nitrogen
Zdroj:	Bulletin des Sociétés Chimiques Belges. 81:307-310
ISSN:	0037-9646
DOI:	10.1002/bscb.19720810126
Popis:	Nicotinamide complexes of the following general composition were prepared: [ML2] [Hgl4], [ML2] [Hg(SCN)4] and ML2(SCN)2, (L = ligand; M Cu2+, Ni2+, Co2+, Fe2+ and Zn2+). As shown by spectroscopic (IR) results, coordination is achieved by the pyridine nitrogen (C N), and not by the amidic one ( ). The location of the vc-s and VCN bands supports the existence of a thiocyanatoisothiocyanato isomerism.
Databáze:	OpenAIRE
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