Monolithic nickel foam supported macro-catalyst: Manipulation of charge transfer for enhancement of photo-activity
| Autor: | Yixing Yuan, Fuyi Cui, Yuan Guo, Bao Xian, Yanei Xue, Penghui Shao, Bing Zhang, Wenxin Shi |
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| Rok vydání: | 2021 |
| Předmět: |
Work (thermodynamics)
Materials science General Chemical Engineering Rational design chemistry.chemical_element Charge (physics) 02 engineering and technology General Chemistry 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences Industrial and Manufacturing Engineering 0104 chemical sciences Catalysis Nickel Chemical engineering chemistry Photocatalysis Environmental Chemistry Particle 0210 nano-technology Layer (electronics) |
| Zdroj: | Chemical Engineering Journal. 418:129456 |
| ISSN: | 1385-8947 |
| DOI: | 10.1016/j.cej.2021.129456 |
| Popis: | The dimensions and structure of conventional photocatalysts severely limit their industrial applications. In view of this, a novel monolithic supported macroscopic catalysts (SMCs) was successfully designed and developed for the first time. The visible-light responsive and reusable Zn0.95Fe0.05S@TiO2/nickel foam (ZFS@TiO2/NF) SMCs was assembled with ZFS particle catalyst as a light responder that was protected by defective TiO2 as a carriers capture layer, the multihole and flexile nickel foam material was induced into photocatalytic system with the function of supporting and charge storage. This integrated material exhibited an unprecedentedly high utilization of carriers by a new set of unique “generation-capture-migration-utilization” path, which was attributed to the key properties of the integration of three independent materials. Furthermore, the loading operation can maximum exert dimensions and interfaces optimization of ZFS and TiO2. This work proposes a novel mechanism of charge transfer for rational design of macro photocatalysts. |
| Databáze: | OpenAIRE |
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