Fermi resonance in condensed CF4 and CCl4
Autor: | J. J. Comeford, Stanley Abramowitz |
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Rok vydání: | 1965 |
Předmět: | |
Zdroj: | Spectrochimica Acta. 21:1479-1486 |
ISSN: | 0371-1951 |
DOI: | 10.1016/0371-1951(65)80060-1 |
Popis: | The infrared absorption spectra of CF 4 and CCl 4 have been observed in both the pure form and in rare gas matrices at low temperatures. The region studied corresponded to the ν 3 , 2ν 4 , and ν 3 , ν 1 +ν 4 Fermi doublets of CF 4 and CCl 4 respectively. The interaction of the vibrations in Fermi resonance in these molecules changes considerably from that found in the gaseous phase. The spectral features observed are discussed and related to S trizhevskii's theory. |
Databáze: | OpenAIRE |
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