Electron transfer initiated photocylizations of N-allylpridinium and quinolinium salts

Autor:	Ung Chan Yoon, Patrick S. Mariano, Jerome L. Stavinoha, Rosemarie Swanson, Suzanne L. Quillen, Elliott Bay
Rok vydání:	1982
Předmět:	Electron transfer Diradical Chemistry Intramolecular force Organic Chemistry Drug Discovery Moiety Photochemistry Biochemistry Catalytic hydrogenation
Zdroj:	Tetrahedron Letters. 23:919-922
ISSN:	0040-4039
DOI:	10.1016/s0040-4039(00)86983-x
Popis:	Results from study of the photochemistry of N-allylpyridinium and -quinolinium perchlorates demonstrate tht intramolecular electron transfer occurs to generate cation diradical precursors of products containing the tetrahydroindolizidine moiety. Catalytic hydrogenation of the crude photolysates leads to production of perhydroindolizidines in synthetically useful yields.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::b815a9a8d64704dc2691952d8243fd86 https://doi.org/10.1016/s0040-4039(00)86983-x Zobrazit plný text záznamu