Reactions of aliphatic fluoro-alcohols with CHClF2 at atmospheric pressure

Autor:	Masanori Tamura, Akira Sekiya, Heng-dao Quan, Yasuhisa Matsukawa, Junji Mizukado
Rok vydání:	2006
Předmět:	Reaction mechanism Organic Chemistry Acetal Chlorodifluoromethane Diglyme Ether Biochemistry Inorganic Chemistry Solvent chemistry.chemical_compound chemistry Yield (chemistry) Environmental Chemistry Organic chemistry Physical and Theoretical Chemistry Selectivity
Zdroj:	Journal of Fluorine Chemistry. 127:400-404
ISSN:	0022-1139
DOI:	10.1016/j.jfluchem.2005.12.034
Popis:	The reactions of aliphatic fluoro-alcohols with chlorodifluoromethane (CHClF 2 ) at atmospheric pressure were examined. In the reaction of CF 3 CF 2 CH 2 OH, the difluoromethylated ether was obtained in moderate yield by using ethers such as 1,4-dioxane, diglyme and THF, or their mixtures with water as a reaction solvent. While acetal and orthoformate were also produced, the selectivity of the difluoromethylated ether could be improved by adding water to the reaction. The effect of water could be explained by the reaction mechanism.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::b809bcf4c4c9ec140f6150a628bfb36a https://doi.org/10.1016/j.jfluchem.2005.12.034 Zobrazit plný text záznamu Full Text from ScienceDirect