Macropolyhedral boron-containing cluster chemistry

Autor:	Suzanne L. Shea, Peter MacKinnon, Mark Thornton-Pett, John D. Kennedy
Rok vydání:	2005
Předmět:	Inorganic Chemistry Vertex (graph theory) Base (group theory) Crystallography Chemistry Product (mathematics) Cluster chemistry Boron containing Materials Chemistry Nuclear magnetic resonance spectroscopy Physical and Theoretical Chemistry
Zdroj:	Inorganica Chimica Acta. 358:1709-1714
ISSN:	0020-1693
DOI:	10.1016/j.ica.2004.07.063
Popis:	Reaction of [{RuCl2(η6-MeC6H4isoPr)}2] with syn-[B18H22] and non-nucleophilic base results in [8-(η6-MeC6H4isoPr)-8-RuB17H21], of 18-vertex anti 10-vertex-nido-10-vertex-nido configuration, as the predominant product. The syn → anti configurational change arises from a trans-cluster pseudo-vertex-substitution of a {BH} vertex by the {Ru2(η6-MeC6H4isoPr)} centre.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::b8029943b8cbb2f6486246b9df0d004c https://doi.org/10.1016/j.ica.2004.07.063 Zobrazit plný text záznamu Full Text from ScienceDirect