Studies on Heterocyclic Analogs of Azulenes. IV. Behavior of 2-Chlorocyclohepta[b]pyrrole Derivatives toward Phosphorus Ylide

Autor:	Tarozaemon Nishiwaki, Kaoru Miura, Noritaka Abe, Kozue Ishida
Rok vydání:	1978
Předmět:	chemistry.chemical_classification Chemistry Ylide Phosphorus chemistry.chemical_element Organic chemistry General Chemistry Carbon-13 NMR Pyrrole derivatives
Zdroj:	Bulletin of the Chemical Society of Japan. 51:1573-1574
ISSN:	1348-0634 0009-2673
DOI:	10.1246/bcsj.51.1573
Popis:	The transylidation reaction of methyl(triphenylphosphoranylidene)acetate with 2-chlorocyclohepta[b]pyrrole derivatives has been studied. 3,8-Disubstituted derivatives gave a transylidation product only, whereas 3-substituted derivatives afforded not only a transylidation products but also the compounds formed by the addition of ylide at C-8. 13C NMR spectra of the transylidation products are recorded in part.
Databáze:	OpenAIRE
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