Oxidative cyclocondensation of thio(seleno)-amides and ureas 1. 2-thioxo-4-quinazolone

Autor: V. P. Bruskov, Kh. M. Shakhidoyatov, M. A. Ashirmatov, N. I. Mukarramov, B. A. Urakov
Rok vydání: 1996
Předmět:
Zdroj: Chemistry of Heterocyclic Compounds. 32:728-731
ISSN: 1573-8353
0009-3122
DOI: 10.1007/bf01164875
Popis: It has been found for the first time that 2-thioxo-4-quinazolone in the presence of acid catalysts in dimethyl sulfoxide is converted to8H,15H-1, 2, 4-thiadiazolo[3, 2-b:5, 4-b′]diquinazoline-8,15-done. The reaction proceeds via oxidative cyclocondensation. The formation of this structure in preference to five other proposed isomers is substantiated using quantum-chemical methods.
Databáze: OpenAIRE