Oxidative cyclocondensation of thio(seleno)-amides and ureas 1. 2-thioxo-4-quinazolone
Autor: | V. P. Bruskov, Kh. M. Shakhidoyatov, M. A. Ashirmatov, N. I. Mukarramov, B. A. Urakov |
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Rok vydání: | 1996 |
Předmět: | |
Zdroj: | Chemistry of Heterocyclic Compounds. 32:728-731 |
ISSN: | 1573-8353 0009-3122 |
DOI: | 10.1007/bf01164875 |
Popis: | It has been found for the first time that 2-thioxo-4-quinazolone in the presence of acid catalysts in dimethyl sulfoxide is converted to8H,15H-1, 2, 4-thiadiazolo[3, 2-b:5, 4-b′]diquinazoline-8,15-done. The reaction proceeds via oxidative cyclocondensation. The formation of this structure in preference to five other proposed isomers is substantiated using quantum-chemical methods. |
Databáze: | OpenAIRE |
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