Spectroscopic study of crystalline Nd2O2S: Optical absorption measurements, crystal field analysis and intensity calculations
| Autor: | M. Chertanov, J. Dexpert-Ghys, O.K. Moune, M. Guittard, M.D. Faucher, B. Piriou |
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| Rok vydání: | 1994 |
| Předmět: |
Absorption spectroscopy
Electronic correlation business.industry Chemistry Energy level splitting Biophysics General Chemistry Field analysis Condensed Matter Physics Biochemistry Molecular physics Atomic and Molecular Physics and Optics Crystal Optics business Absorption (electromagnetic radiation) Multiplet Intensity (heat transfer) |
| Zdroj: | Journal of Luminescence. 59:231-246 |
| ISSN: | 0022-2313 |
| DOI: | 10.1016/0022-2313(94)90002-7 |
| Popis: | Room temperature and low temperature optical absorption measurements are performed on Nd2O2S in crystal and powder form. The experimental oscillator strengths are deduced and compared with calculations at 8 and 300 K including the contribution of Judd-Ofelt and Jorgensen-Judd mechanisms. The global oscillator strengths are satisfactorily reproduced by considering the sum of both contributions but the relative intensities of the strong transitions are best reproduced by the Jorgensen-Judd mechanism alone. |
| Databáze: | OpenAIRE |
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