Synthesis of homochiral 3-substituted cyclopentanones from 2-norbornanones

Autor:	E. Teso Vilar, A. Garcia Martinez, S. De La Moya Cerero, A. Garcia Fraile, P. Martinez Ruiz, L. R. Subramanian
Rok vydání:	1996
Předmět:	Inorganic Chemistry chemistry.chemical_compound Hydrolysis chemistry Fragmentation (mass spectrometry) Organic Chemistry Periodate Organic chemistry Physical and Theoretical Chemistry Norbornane Cleavage (embryo) Catalysis
Zdroj:	Tetrahedron: Asymmetry. 7:2177-2180
ISSN:	0957-4166
DOI:	10.1016/0957-4166(96)00264-9
Popis:	The cleavage of the C 1 -C 2 bond in norbornane derivatives is accomplished by base-promoted hydrolysis of α-nitroketones, periodate oxidation or Beckmann fragmentation of suitable precursors prepared from the 2-norbornanones 1 . These reactions are the basis for the synthesis of the 3-substituted homochiral cyclopentanones 6 , 10 or 15 .
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::b7bd99d113f63a1e74bda834e788c0b1 https://doi.org/10.1016/0957-4166(96)00264-9 Zobrazit plný text záznamu Full Text from ScienceDirect