Characteristically steric effects of substituent on bidirectional inclusion complexation of α-substituted phenyl-2,4,6-trimethoxybenzyl(t-butyl)nitroxides with β-cyclodextrins

Autor:	Tadashi Hanaya, Keitaro Miyazono, Yoshimi Sueishi
Rok vydání:	2015
Předmět:	Steric effects chemistry.chemical_compound Molecular recognition chemistry Stereochemistry Side chain Substituent Molecule General Chemistry β cyclodextrins Condensed Matter Physics Food Science
Zdroj:	Journal of Inclusion Phenomena and Macrocyclic Chemistry. 83:193-197
ISSN:	1573-1111 1388-3127
DOI:	10.1007/s10847-015-0537-4
Popis:	Using unique guest probes having more than one bulky group, we demonstrate substituent dependence on group inclusion for the molecular recognition of β-cyclodextrins (β-CDs). Group-inclusion equilibrium with 6-O-α-D-glucosyl-β-cyclodextrin (G-β-CD) having a bulky glucosyl side chain has been shown to be significantly altered as compared with unmodified β-CD. We suggest that the bulky substituents in guest and host molecules play an important role for the group inclusion of molecular recognition.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::b7a97ebc5a043a98cbefb6b151a5bd40 https://doi.org/10.1007/s10847-015-0537-4 Zobrazit plný text záznamu Full text from SpringerLink