The preparation and properties of the UC1-xNx solid solutions by pulses laser carbonitriding
| Autor: | Yongbin Zhang, Chuan Mo, Lei Lu, Qinguo Wang, Yin Hu, Yanping Wu, Zhilei Chen, Huoping Zhong, Xue Jiang, Kezhao Liu, Dingmu Lang |
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| Rok vydání: | 2019 |
| Předmět: |
Materials science
Carbonitriding Mechanical Engineering Uranium dioxide Metals and Alloys Analytical chemistry chemistry.chemical_element 02 engineering and technology Partial pressure Uranium 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences Hardness 0104 chemical sciences Corrosion chemistry.chemical_compound chemistry Mechanics of Materials Phase (matter) Materials Chemistry 0210 nano-technology Solid solution |
| Zdroj: | Journal of Alloys and Compounds. 774:779-786 |
| ISSN: | 0925-8388 |
| Popis: | The UC1-xNx solid solution modified layers that improve corrosion resistance and surface hardness of uranium were prepared by pulsed laser irradiating the surface uranium in the mixed atmospheres where the partial pressure ratios of CH4 to N2 are 1:2, 1:1 and 2:1, respectively. The SEM images show that the distribution of micro-cracks in the modified layers decreases significantly with the increase of partial pressure of CH4 in the mixed atmospheres. The phase structure and chemical composition of the modified layers were investigated by XRD and AES. XRD results show that the composition of the carbonitride modified layers is mainly UC1-xNx solid solution, only with a small amount of free uranium and uranium dioxide. AES results reveal that the C and N contents in the UC1-xNx solid solution can be adjusted by the respective partial pressure of CH4 and N2. The U 4f, N 1s and C 1s core-level also confirmed that the UC1-xNx solid solution is the main component in the laser modified layers. Electrochemical polarization tests were conducted in 0.02 mol/L NaCl solution and the results indicated that the carbonitride modified layer prepared in an atmosphere where the ratio of CH4 to N2 at 1:2 have excellent corrosion resistance, its self-corrosive potential and self-corrosive current are −2.28 × 10−1 V and 5.56 × 10−8 A/cm2, respectively, while the values of the uranium are −5.67 × 10−1 V and 8.08 × 10−7 A/cm2, respectively. Nano-indentation measurement results show that the average hardness at different depths of these modified layers is between 7 GPa and 9 GPa, while the average value of the uranium is 4.1 GPa. |
| Databáze: | OpenAIRE |
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