Langmuir-Blodgett film assembly of Cu-phthalocyanine derivatives substituted by methacrylate oligomer chains

Autor:	Katsuyuki Naito, Akira Miura, Makoto Azuma
Rok vydání:	1992
Předmět:	Infrared Chemistry Metals and Alloys Substituent Surfaces and Interfaces Substrate (electronics) Methacrylate Oligomer Langmuir–Blodgett film Surfaces Coatings and Films Electronic Optical and Magnetic Materials chemistry.chemical_compound Polymer chemistry Monolayer Materials Chemistry Side chain
Zdroj:	Thin Solid Films. :527-530
ISSN:	0040-6090
DOI:	10.1016/0040-6090(92)90332-6
Popis:	LB film forming properties of copper-phthalocyanine (Cu-Pc) derivatives substituted with various methacrylate oligomers attached to the parent Pc were investigated. The monolayer properties were markedly affected by the methacrylate side chains employed and the ethyl- and n-butylmethacrylate co-oligomer substituent produced a stable and fluid film on a water surface and yielded a Y-type LB film. The film surface deposited onto hydrophobic substrate was found to be smooth and homogeneous. The molecular orientation was determined by X-ray diffraction and visible and Fourier transform infrared polarized spectra. The molecular structures suitable for uniform LB films including Cu-Pc are discussed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::b79679c0bd390f543e9dba861be575b5 https://doi.org/10.1016/0040-6090(92)90332-6 Zobrazit plný text záznamu