Bubble point pressures of binary mixtures of ethanol with propane, dimethyl ether or trans-1,3,3,3-tetrafluoropropene and correlation with equations of state and Wong-Sandler mixing rules
| Autor: | Tomoya Tsuji, Nabilah Zaini, Katsuto Otake, Taka-aki Hoshina, Misaki Nakazawa, Atsumasa Yoshida, Andrea Jia Xin Lai |
|---|---|
| Rok vydání: | 2020 |
| Předmět: |
Propellant
Activity coefficient Equation of state 010405 organic chemistry Chemistry General Chemical Engineering General Physics and Astronomy Thermodynamics 02 engineering and technology 01 natural sciences 0104 chemical sciences chemistry.chemical_compound 020401 chemical engineering Propane Non-random two-liquid model Dimethyl ether Bubble point 0204 chemical engineering Physical and Theoretical Chemistry Mixing (physics) |
| Zdroj: | Fluid Phase Equilibria. 522:112764 |
| ISSN: | 0378-3812 |
| Popis: | For the design of spray propellants, bubble point pressures were measured for binary mixtures of ethanol with propane, dimethyl ether (DME) or trans-1,3,3,3-tetrafluoropropene (R1234ze(E)), with a static type apparatus at (293.15–313.15) K. Experimental data were correlated with the Peng-Robinson (PR) and Stryjek-Vera (PRSV) equations of state using the Wong-Sandler (WS) mixing rules. The NRTL activity coefficient model in the WS mixing rules was effective for correlation of systems that exhibited large non-idealities (ethanol - propane, ethanol - R1234ze(E)). Correlation of the bubble point pressures with the PRSV equation of state and WS mixing rules was to within an average of 2.391% absolute deviation in pressure for all systems, which is considered to be sufficient for design of spray devices with propellants that have low global warming potential. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|
Full Text from ScienceDirect