Reactions of olefins with elementary sulfur in the presence of triiron dodecacarbonyl
Autor: | V. D. Tyurin, G. G. Aleksandrov, I. V. Petrosyan, B. I. Kolobkov, Yu. T. Struchkov, N. S. Nametkin, A. M. Krapivin |
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Rok vydání: | 1981 |
Předmět: | |
Zdroj: | Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 30:2133-2138 |
ISSN: | 1573-9171 0568-5230 |
Popis: | 1. Dithiolane diiron hexacarbonyl complexes are formed in the reaction of S8 with Fe3(CO)12 in the presence of cyclohexene or 1-hexene. When cyclohexene is used, sulfur atoms are incorporated at the double bond to give cyclic polysulfides. 2. The structure of thiotriiron decarbonyl was investigated by means of x-ray diffraction analysis. |
Databáze: | OpenAIRE |
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