Influence of substituents in salicylaldehyde molecule on interaction with 2-imino-3,5-dimethylthiazolidine

Autor:	S. M. Aldoshin, O. S. Filipenko, Yu. M. Chunaev, L. N. Kurkovskaya, N. A. Martem'yanova, N. M. Przhiyalgovskaya
Rok vydání:	1993
Předmět:	chemistry.chemical_classification chemistry.chemical_compound Base (chemistry) chemistry Salicylaldehyde Stereochemistry Organic Chemistry Molecule Ring (chemistry)
Zdroj:	Chemistry of Heterocyclic Compounds. 29:356-361
ISSN:	1573-8353 0009-3122
DOI:	10.1007/bf00531517
Popis:	Salicylaldehyde, 5-chlorosalicylaldehyde, or o-vanillin will react with 2-imino-3,5-dimethylthiazolidine to form previously unknown bis(3,5-dimethylthiazolidin-2-ylideneamino)-2-hydroxyphenylmethanes. If strong electron-acceptor groups are present on the aromatic ring, an acid-base interaction takes place. Thus, 3-nitro-5-methoxy-, 3-nitro-5-chloro-, and 3-bromo-5-nitrosalicylaldehyde react with the heterocyclic base to form saltlike complexes, the structure of which has been confirmed by x-ray diffraction.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::b76ba44eeebcf54eece644c324aadfdb https://doi.org/10.1007/bf00531517 Zobrazit plný text záznamu Full text from SpringerLink